Effect of halogenation of ortho-positions of tetraphenylporphyrin and its Cd(II) complex on their complexing ability towards d-metal salts in dimethylformamide

DOI: 10.6060/mhc224315m

  • Svetlana V. Zvezdina G.A. Krestov Institute of Solution Chemistry
  • Natalya V. Chizhova G.A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences
  • Nugzar Zh. Mamardashvili G.A. Krestov Institute of Solution Chemistry
  • Oskar I. Koifman G.A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences
Keywords: Halogenophenylporphyrins, metalloporphyrins, intermediate, complexation, metal-exchange reaction

Abstract

The complex formation reactions of 5,10,15,20-tetra(2,6-dichlorophenyl)- and 5,10,15,20-tetra(2,6-difluorophenyl) porphyrins, as well as metal exchange reactions of their Cd(II) complexes with Zn(II) and Co(II) cations in dimethylformamide were investigated by the spectrophotometric method. Effect of the substituent nature in the macrocycle and the salt solvate complex on the coordination and metal exchange reactions was revealed. The kinetic parameters of metal exchange Cd(II)-(2,6-dihalogenophenyl)porphyrins with Zn(II) and Co(II) salts in dimethylformamide were calculated. The mechanism of the metal exchange reaction is proposed, which suggests the formation of a binuclear intermediate. The synthesized compounds were identified using UV–Vis, 1H NMR spectroscopy and mass-spectrometry.

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Published
2022-11-20
How to Cite
Zvezdina, S., Chizhova, N., Mamardashvili, N., & Koifman, O. (2022). Effect of halogenation of ortho-positions of tetraphenylporphyrin and its Cd(II) complex on their complexing ability towards d-metal salts in dimethylformamide. Macroheterocycles, 15(2), 101-108. Retrieved from https://mhc-isuct.ru/article/view/4315
Issue
Vol 15 No 2 (2022)
Section
Porphyrins