Новый 4-Карбоксифенилзамещенный порфиразин, его эфир и их комплексы с Zn(II)
Аннотация
The porphyrazines bearing eight 4-carboxyphenyl and 4-butoxycarbonylphenyl groups (H2Pz(PhCOOH)8 and H2Pz(PhCOOBu)8), as well as their Zn(II) complexes were obtained and characterized by spectral methods. The conversion of carboxyl derivatives into their anionic forms H2Pz(PhCOO-)8 and ZnPz(PhCOO-)8 in the presence of alkali leads to water-soluble species. ZnPz(PhCOOH)8 and ZnPz(PhCOOBu)8 possess the high ability to generate singlet oxygen in DMF solutions (ФΔ = 80-83%), while their metal free analogues are weak photosensitizers due to their aggregation tendency.
Литература
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