Preparation and Electrochemically Catalytic Hydrogen Evolution of Co(III)corrole Copolymerized with Mono-, Bis- and Tri-Thiophenes

  • Yuan Lu
  • Xiaohong Zhang
  • Minzhi Li
  • Weihua Zhu
  • Xu Liang
DOI: https://doi.org/10.6060/245800l

Аннотация

A series of conductive polymers of thiophene-substituted CoШcorrole copolymerized with mono-, bis- and tri-thiophenes have been prepared by electrochemical polymerization. Compared with the CoШcorrole monomer, the electrocatalytic hydrogen evolution performance was significantly improved. In particular, when the molar ratio of CoШcorrole and bithiophene is 10:1, the conductive polymer prepared shows better electrocatalytic hydrogen evolution performance. In addition, when comparing the effect of chain length of thiophene, CoШcorrole-trithiophene showed the greatest improvement on the hydrogen evolution performance, followed by bis- and mono-thiophene.

Литература

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Опубликован
2024-06-24
Как цитировать
Lu, Y., Zhang, X., Li, M., Zhu, W., & Liang, X. (2024). Preparation and Electrochemically Catalytic Hydrogen Evolution of Co(III)corrole Copolymerized with Mono-, Bis- and Tri-Thiophenes. Макрогетероциклы/Macroheterocycles, 17(3), 247-254. https://doi.org/10.6060/245800l
Выпуск
Том 17 № 3 (2024): The issues 2 and 3 are dedicated to the memory of Academician of Russian Academy of Sciences Oskar I. Koifman and coincide with his 80th Anniversary
Раздел
Корролы