Спектрально-люминесцентные и фотофизические свойства свободных оснований корролов

Аннотация

Corroles are the brightest representatives of the contracted tetrapyrrolic macrocycles whose electronic structure, spectral-luminescent and photophysical properties are quite different from those of porphyrins. To date the number of reviews has appeared dealing with the synthesis and applications studies, but much less attention has been paid to the results of the fundamental studies on the electronic structure, aromaticity and photophysics of these compounds. This review aims to summarize the peculiarities of the spectral-luminescent and photophysical properties of the free base corroles unraveled in last twenty years.