От химических димеров порфиринов к сложным мультикомпонентным наноансамблям: некоторые редкие явления и релаксационные процессы
Аннотация
В результате многолетнего и плодотворного сотрудничества с профессором Г.В. Пономаревым и доктором А.М. Шульгой и благодаря их высокому профессионализму на основе подхода «снизу-вверх» были получены высокорганизованные мультипорфириновые комплексы различной морфологии, а также наноансамбли на основе полупроводниковых квантовых точек и порфиринов. С использованием стационарной и время-разрешенной спектроскопии в комбинации с методами высокого спектрального разрешения были обнаружены и исследованы специфические и/или редкие процессы релаксации энергии возбуждения (выжигание спектральных провалов, Т-Т перенос в димерах, фотоиндуцированный перенос электрона при низких температурах, дистанционный перенос заряда по механизму суперобмена и т.д.).
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