The Influence of the Nature of the Spacer Fragment of the Peripheral Substituent on the Catalytic Behavior of Carboxyphenyl-Substituted Phthalocyanine Complexes
Аннотация
Present work reveals the study of catalytic properties of copper and cobalt complexes with phthalocyanine ligands with o-carboxyphenoxy/carboxyphenylsulfanyl/carboxyphenylamino- substituents in the peripheral positions of the macroring. For compounds, the aggregative behavior in aqueous and aqueous-alkaline media was studied. On the example of the reaction of catalytic oxidation of sulfur-containing organic substrates, the rate constants of the formation of the corresponding disulfide were determined. The influence of the nature of the spacer fragment of the peripheral substituent on the activity of the complexes as catalysts for liquid-phase oxidation was revealed.
Литература
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