Palladium-Catalyzed Amination for the Synthesis of Macrocycles and Polymacrocycles: Contribution of Professor I.P. Beletskaya
Аннотация
Данный мини-обзор посвящен вкладу Академика РАН профессора И.П. Белецкой, руководителя Лаборатории элементоорганических соединений Химического факультета МГУ имени М.В. Ломоносова, в стратегию синтеза разнообразных макроциклических и полимакроциклических соединений с использованием реакции палладий-катализируемого аминирования. На протяжении более двух десятилетий эта химия планомерно и успешно развивается, начиная с достаточно простых соединений, переходя к более усложненным молекулам, содержащим несколько макроциклов, а относительно недавно начато исследование соединений, включающих в свой состав флуорофорные и хиральные структурные фрагменты для детектирования катионов металлов и хиральных органических молекул. В результате получены многие сотни соединений – в том числе производные диазакраун-эфиров и тетраазамакроциклов (циклен и циклам), структуры с эндоциклическими ароматическими и гетероароматическими фрагментами. Роль палладий-катализируемого аминирования – ключевого процесса в синтезе всего многообразия такого рода соединений – невозможно переоценить.
Литература
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