N-Олигоэтиленгликоль-имидазолиевые производные тиакаликc[4]арена и каликc[4]арена: различие в солюбилизирующих свойствах и обнаружение аденозинфосфатов
Аннотация
Изучена агрегация амфифильных макроциклов на основе каликс[4]аренов в конфигурации конус и тиа[4]каликсаренов в конфигурации 1,3-альтернат с N-олигоэтиленгликоль-имидазолиевыми фрагментами в водной среде. Продемонстрировано, что как образующиеся агрегаты, так и индивидуальные макроциклы обладают способностью солюбилизировать гидрофобный краситель Оранж ОТ. Солюбилизирующая емкость существенно возрастает при переходе от каликс[4]ареновой к тиакаликс[4]ареновой платформе. Исследовано взаимодействие каликс[4]аренов и тиа[4]каликсаренов с дианионным красителем Эозином Н методами УФ-видимой и флуоресцентной спектрофотомерии. Методом конфокальной микроскопии изучены размеры образующихся комплексов макроцикл – Эозин Н. Установлено, что размеры агрегатов варьируются от 350 до 750 нм. Показано, что комплексы макроцикл – Эозин Н могут использоваться в роли сенсоров на аденозинфосфаты, причем система тиакаликс[4]арен – Эозин Н проявляет селективность к аденозинтрифосфату
Литература
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