Magnetocaloric properties of lanthanide tetrapyrrole complexes above Curie temperature

DOI: https://doi.org/10.6060/mhc224441b
Ключевые слова: магнитокалорический эффект, теплоемкость, комплексы тербия, порфирины, фталоцианин

Аннотация

To obtain the fundamental knoledge in the field of magnetocaloric behavior of new molecular materials at room temperature, we have synthesized (5,10,15,20-tetraphenylporphinato)terbium(III), (5,10,15,20-tetra(4-tertbutylphenylporphinato)terbium(III), and (phthalocyaninato)terbium(III) chlorides and have fully characterized their chemical structure using spectral methods (UV-vis, IR, 1H NMR, MALDI TOF). The specific heat capacities of paramagnets synthesized were measured at the temperatures from 224 to 393 K in zero fields by means of DSC method. Magnetocaloric effect, heat, and charge of enthalpy/entropy during the magnetization were observed over the temperature range of 278 - 328 K in magnetic fields from zero to 1 T by the direct microcalorimetric method. Using the analysis of the temperature dependences of the magnetocaloric parameters in lanthanide row, we have established that the control of the magnetic exchange between the spin carrier and the paramagnetic ligand is determined both by the fine tuning of the outer shell of the lanthanide ion and by the substitution in the macrocycle. It was shown at a quantitative level that the terbium ion in the tetrapyrrole complexes carries out the magnetic exchange in 4f75d1 configuration.

Биографии авторов

Tatyana N. Lomova, Институт химии растворов им. Г. А. Крестова Российской академии наук

Заведующая лабораторией синтеза и реакционной способности металлопорфиринов в растворах, главный научный сотрудник

Victor V. Korolev, Институт химии растворов им. Г. А. Крестова Российской академии наук

Ведущий научный сотрудник, Лаборатория физической химии гетерогенных систем полимер - жидкость

Anna G. Ramazanova, Институт химии растворов им. Г. А. Крестова Российской академии наук

Лаборатория Физическая химия гетерогенных систем полимер - жидкость

Olga V. Balmasova, Институт химии растворов им. Г. А. Крестова Российской академии наук

Лаборатория Физическая химия гетерогенных систем полимер - жидкость, научный сотрудник

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Опубликован
2023-12-19
Как цитировать
Lomova, T., Korolev, V., Ramazanova, A., & Balmasova, O. (2023). Magnetocaloric properties of lanthanide tetrapyrrole complexes above Curie temperature. Макрогетероциклы/Macroheterocycles, 16(4), 266-274. https://doi.org/10.6060/mhc224441b
Выпуск
Том 16 № 4 (2023)
Раздел
Порфирины